The first phosphoramide–mercury(II) complex with a Cl2Hg–OP[N(C)(C)]3segment
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چکیده
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15 صفحه اولFirst paramagnetic Pd(II) complex with a PdN4S2 coordination core.
Reaction of the potassium salt of N-thiophosphorylated thiourea 2-PyNHC(S)NHP(S)(OiPr)(2) (HL) with PdCl(2) in aqueous MeOH leads to the formation of two mononuclear homoleptic complexes [Pd{2-PyNHC(S)NP(S)(OiPr)(2)-1,5-S,S'}(2)] ([Pd(L-1,5-S,S')(2)]) and [Pd{2-PyNHC(S)NP(S)(OiPr)(2)-1,5,7-N,N',S}(2)] ([Pd(L-1,5,7-N,N',S)(2)]), while the mechanically induced solid-state reaction of KL and PdCl(...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section C Structural Chemistry
سال: 2016
ISSN: 2053-2296
DOI: 10.1107/s2053229616002394